procedure TForm1.FormCreate(Sender: TObject);
var
app: HWND;
begin
//Application.Title := 'New Application Title';
app := GetWindow(WindowHandleToPlatform(Self.Handle).Wnd, GW_OWNER);
SetWindowText(app, 'New Application Title');
end;
Check out the thread on the official forums about it.
Set The Application Title In Delphi XE5 Firemonkey On IOS Android Windows And OSX
